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HomeMy WebLinkAboutTe Velde 29-28HZ - Air Monitoring Program/Report - Kerr McGee - 7/31/2021 (2) July 31, 2021 Kerr-McGee Oil & Gas Onshore LP 1099 18th Street Denver, CO 80202 720-929-6000 Marty Ostholthoff - LGD and Planning Manger Nancy D. Chick 151 Grant Avenue Physical Science Researcher P.O. Box 100 CDPHE Firestone, CO 80520 4300 Cherry Creek Drive S. Denver, CO 80246-1530 Mr. Taylor Robinson Environmental Health Specialist Mr. Jason Maxey OGED Director and Local Government Designee Oil & Gas Energy Department 1301 N. 17th Ave. Greeley, CO 80631 Re: Air Monitoring Program: Te Velde 29-28HZ Pad and Production Facility Weld County, Colorado In accordance with CDPHE Regulation 7 VI.C.2.b, Kerr-McGee is submitting the Air Monitoring Report for Production Rig Drilling and DUCs monitoring from June 1 through 30, 2021 for this location. Kerr-McGee has contracted Montrose Air Quality Services, LLC (Montrose) to perform the air monitoring at this location. Attached is the Air Monitoring Report prepared by Montrose Air Monitoring was conducted in accordance with the Kerr-McGee Air Monitoring Program approved by CDPHE in a letter dated April 20, 2021. Results from 35 air samples from carbon desorption tubes and SUMMA® canisters are included in this report. All results are below the health guidance values (HGVs) guidelines compiled by the Colorado Department of Public Health and Environment (CDPHE). The Air Monitoring Program establishes three (3) levels of investigation responses to ensure protection of public health, safety, welfare, the environment, and wildlife resources. Sections 8 and 9 of the air monitoring program detail these levels and responses. If a Level 3 event occurs, Kerr-McGee will notify the CDPHE and local government with jurisdiction over this pad within 48 hours of receiving notification. There were no readings from the continuous PID analyzers or analytical results above the Investigation Levels. If you have any questions, please contact Chad Schlichtemeier at Chad_Schlichtemeier@oxy.com. AMBIENT MONITORING REPORT TE VELDE 29-28HZ PAD PRE-OPERATIONS AND DRILLING PHASE KERR-MCGEE OIL & GAS ONSHORE LP Prepared For: Kerr-McGee Oil & Gas Onshore LP 1099 18th St #1800 Denver, Colorado 80202 Prepared By: Montrose Air Quality Services, LLC 990 W. 43rd Avenue Denver, Colorado 80211 Document Number: 017AA-008129-RT-23 Reporting Period: June 1 through June 30, 2021 Drilling Period: June 6 through June 23, 2021 DUCs Monitoring: June 24 – August 13, 2021 Report Date: July 31, 2021 Kerr-McGee Oil & Gas Onshore LP Report ID: 017AA-008129-RT-23 Page 4 Table of Contents PROJECT OVERVIEW ............................................................................................................................... 5 Summary ...................................................................................................................................................... 5 Project Scope ............................................................................................................................................... 5 Contact Information .................................................................................................................................... 5 Well Pad Site Description............................................................................................................................ 5 Sampling Locations for Production Monitoring .......................................................................................... 6 Sampling Locations for DUCs Monitoring .................................................................................................. 7 Methodology ................................................................................................................................................ 9 Phase of Operation and Activities During Reporting Period .................................................................... 10 Summary of Down Time or Equipment Malfunction ................................................................................. 10 Summary of Investigations and Response .................................................................................................. 10 Discussion of Results ................................................................................................................................. 11 SUMMARY OF RESULTS ........................................................................................................................ 12 Figure 1 – Te Velde 29-28HZ Southeast VOC Data.................................................................................. 12 Figure 2 – Te Velde 29-28HZ Southwest VOC Data ................................................................................. 13 Figure 3– Te Velde 29-28HZ West VOC Data .......................................................................................... 14 Figure 4 – Te Velde 29-28HZ East VOC Data .......................................................................................... 15 Table 1 – Te Velde VOC Data Analysis ..................................................................................................... 16 Figure 5 – Te Velde 29-28HZ Meteorological Data ................................................................................. 17 Table 2 –Passive Sampling Results ........................................................................................................... 18 Table 3 –Passive Sampling Results ........................................................................................................... 19 Table 4 –Summa Canister Results and Rig Activity................................................................................... 20 APPENDIX A: CALIBRATION AND QA/QC DATA APPENDIX B: FIELD DATA SHEETS APPENDIX C: CALIBRATION GAS CERTIFICATION SHEETS APPENDIX D: API AND AIRS NUMBERS APPENDIX E: OPERATIONS ACTIVITY APPENDIX F: INVESTIGATION LEVEL EVENT DESCRIPTIONS Kerr-McGee Oil & Gas Onshore LP Report ID: 017AA-008129-RT-23 Page 5 Project Overview Summary Montrose Air Quality Services, LLC (Montrose) was contracted by Kerr-McGee Oil & Gas Onshore LP (Kerr-McGee) to conduct air monitoring at the Te Velde 29-28HZ Pad. This report covers the reporting period from May 14 through June 30, 2021, during Pre- Operations, Production Drilling, and the period between drilling and completions (DUCs). Pre-Operations monitoring began on May 14 through June 5, 2021. Production Drilling monitoring occurred from June 6, 2021 to June 23, 2021. DUCs monitoring began on June 24, 2021. Air Monitoring was conducted in accordance with the Kerr-McGee Air Monitoring Program approved by CDPHE in a letter dated April 20, 2021. All air samples taken during the reporting period were well below the Health Guidance Values (HGVs) compiled by the CDPHE. There were no readings from the continuous PID analyzers or analytical results above the Investigation Levels. Project Scope Continuous monitoring for VOCs and passive sampling for benzene commenced on May 14, 2021. The PID analyzers (named “SPOD”) used around the Te Velde 29-28HZ facility were manufactured by SENSIT. Each sensor is solar powered and transmits data to the data platform via LTE cell technology. The data is 128-bit encrypted during transmission. Four (4) sensors monitored for VOCs and one (1) for the meteorological parameters during the reporting period. All sampling was performed by Montrose. Contact Information The contact information for each of the principal parties is summarized in the tables below: Chad Schlichtemeier Austin Heitmann Occidental Montrose Air Quality Services, LLC 1099 18th Street 990 West 43rd Ave Denver, CO 80202 Denver, CO 80216 Phone: (720) 929-6867 Phone: (303) 670-0530 E-mail: Chad_Schlichtemeier@Oxy.com E-mail: AHeitmann@Montrose-Env.com Well Pad Site Description The Kerr-McGee Te Velde 29-28HZ well pad facility location. Latitude Longitude Te Velde 29-28HZ Pad 40.115633 -104.899865 Parent Well Code 1123051235068 Legal Description: NNW 28 2N 67W 6 PM The API number of the wells and any associated facility or equipment AIRS numbers can be found in Appendix D. Kerr-McGee Oil & Gas Onshore LP Report ID: 017AA-008129-RT-23 Page 6 Sampling Locations for Production Monitoring Sampling locations are labeled by ID on the map below. The GPS coordinates of the locations are listed in the following table. Location ID GPS Coordinates Distance from Facilities (ft) Monitoring Technology T9 40.11406, -104.89612 300 PID Analyzer, Carbon Sorbent Tube T10 40.114357, -104.899150 165 Carbon Sorbent Tube T11 40.114366, -104.899656 165 Carbon Sorbent Tube T12 40.114344, -104.900292 165 Carbon Sorbent Tube T13 40.114051, -104.901119 300 PID Analyzer, Carbon Sorbent Tube T14 40.114928, -104.900937 120 Carbon Sorbent Tube Kerr-McGee Oil & Gas Onshore LP Report ID: 017AA-008129-RT-23 Page 7 Location ID GPS Coordinates Distance from Facilities (ft) Monitoring Technology T15 40.115652, -104.90023 120 Carbon Sorbent Tube T16 40.116132, -104.900866 120 Carbon Sorbent Tube T17 40.115577, -104.901473 250 PID Analyzer, Carbon Sorbent Tube T18 40.116727, -104.900294 165 Carbon Sorbent Tube T19 40.116759, -104.899747 165 Carbon Sorbent Tube T20 40.116704, -104.899125 165 Carbon Sorbent Tube T21 40.115868, -104.897742 165 Carbon Sorbent Tube T22 40.115564, -104.897744 165 Carbon Sorbent Tube T23 40.115195, -104.897746 165 Carbon Sorbent Tube T24 40.115504, -104.896630 300 PID Analyzer, Carbon Sorbent Tube Sampling Locations for DUCs Monitoring Production drilling was completed on 6/23/21. In compliance with the monitoring plan for DUCs all non-PID analyzer locations were removed and four (4) PID analyzers with collocated carbon sorbent tubes were left in place as the map below describes. Sampling locations are labeled by ID on the map below. Kerr-McGee Oil & Gas Onshore LP Report ID: 017AA-008129-RT-23 Page 8 The GPS coordinates of the locations are listed in the following table. Location ID GPS Coordinates Distance from Facilities (ft) Monitoring Technology T9 40.11406, -104.89612 300 PID Analyzer, Carbon Sorbent Tube T13 40.114051, -104.901119 300 PID Analyzer, Carbon Sorbent Tube T17 40.115577, -104.901473 250 PID Analyzer, Carbon Sorbent Tube T24 40.115504, -104.896630 300 PID Analyzer, Carbon Sorbent Tube Kerr-McGee Oil & Gas Onshore LP Report ID: 017AA-008129-RT-23 Page 9 Methodology Continuous Monitoring The monitoring on the perimeter of the well pad is being performed using PID VOC analyzers. In the device sampling occurs by allowing the ambient air to passively enter the devices exterior housing via small holes and pass over the surface of the sensor. Each device used in this project is solar powered and transmits data via cellular. A PID sensor contains a lamp that produces photons that carry enough energy to break molecules into ions. The PID will only respond to molecules that have an ionization energy at or below the energy of the lamp, the PID used on this project employs a 10.6 electron- volt lamp. The produced ions then generate an electrical current that is measured as the output of the detector. The PID used in this monitoring campaign is manufactured by IonScience, a United Kingdom company. The sensor mitigates the traditional PID issue of humidity bias, by installing a hydrophobic filter between the lamp and the ambient air. Water molecules are deterred from entering the ion producing chamber and absorbing radiation. The PID themselves are also heated slightly above ambient temperature to improve stability of the detector. All continuous monitoring equipment operation and maintenance procedures followed the Quality Assurance Project Plan provided in the Kerr-McGee Air Monitoring Program. Carbon Sorbent Tubes For the passive sorbent tube sampling portion of this test program, EPA Method 325A/B entitled “Volatile Organic Compounds from Fugitive and Area Sources” was followed for both sampling and analysis methodology. The study incorporated passive sampling for Benzene utilizing Carbopack X™ tubes. The tube is a stainless steel net cylinder, with 100 mesh grid opening and 5.8 mm diameter, packed with 530 ± 30 mg of activated charcoal with particle size 35-50 mesh. Volatile organic compounds are trapped by adsorption. The tube is desorbed using a thermal desorber and the extract is analyzed using GC/MS. Benzene concentrations are calculated using the mass of each compound found, the validated Carbopack X™ uptake rates, time sampled, and average field temperature. Field-ready passive samplers were provided in a background-free cooler by Enthalpy Analytical, LLC (Enthalpy) in Durham, North Carolina. Tubes are individually packaged in individual sealed glass vials prevent protection against contamination. The cooler included ice packs to keep the sampled tubes cool throughout the shipping process. All Carbon Sorbent Tube field sampling followed the SOP provided in the Kerr-McGee Air Monitoring Program. Kerr-McGee Oil & Gas Onshore LP Report ID: 017AA-008129-RT-23 Page 10 SUMMA® Canister For the summa canister sampling portion of this test program, EPA Compendium Method TO-15 entitled “Determination of Volatile Organic Compounds (VOCs) in Air Collected in Specially Prepared Canisters and Analyzed by Gas Chromatography/Mass Spectrometry (GC/MS)” (“Method TO-15”) was followed for both sampling and analysis methodology. Entech Instruments Silonite™ CS1200E Passive Canister Samplers were used to collect samples over each 24-hour period. The Entech canisters used were six-liter stainless canisters lined with ultra-inert surface coatings. The canisters were cleaned and blanked for use according to laboratory standard operating procedures. The canister samples were shipped to the Enthalpy laboratory where the samples were analyzed for benzene, toluene, ethylbenzene, and xylenes. All SUMMA® canister field sampling followed the SOP provided in the Kerr-McGee Air Monitoring Program. Phase of Operation and Activities During Reporting Period In Appendix E is the operational activity during the reporting period. Summary of Down Time or Equipment Malfunction The PID Analyzers data recovery, which includes equipment malfunctions, during the reporting period are shown in the table below. The post-monitoring bump test results for June on PID analyzer at location T17 was outside the range set in the Quality Assurance Project Plan (QAPP). The procedures outlined in the QAPP, which is part of the approved Kerr-McGee Air Monitoring Program, were followed. A full three-point calibration was conducted on the unit and the analyzer was thoroughly inspected. The equipment passed QA/QC checks and the bump test demonstrated the units were still linear. The units seemed to have drifted more than is typical over a one-month period, which is not unusual for monitors of this type. The analyzer data is valid but data for the month of April for these analyzers may be biased high. No correction was applied to the data. Summary of Investigations and Response The Kerr-McGee Air Monitoring Program establishes Investigation Levels for the continuous monitors and analytical results. If an Investigation Level is triggered, the monitoring program outlines an Investigation Level Response for each level. Location ID T-9 T-13 T-17 T-24 Data Recovery (%) 99.8% 99.8% 99.8% 94.2% Kerr-McGee Oil & Gas Onshore LP Report ID: 017AA-008129-RT-23 Page 11 During this reporting period, there were no continuous monitor readings or analytical results that exceeded an Investigation Level. Investigation event responses, if applicable, can be found in Appendix F. Investigation Level 3: No notifications to CDPHE and the local government with jurisdiction over the location of the operations within forty-eight (48) hours of responsive action(s) taken as a result of recorded values in excess of the Investigation Level 3 were required. Discussion of Results The 15-minute block averages for the PID VOC results for all Production sampling can be found in Figures 1 through 4. The data distribution for the PID VOC results can be found in Table 1. All 14-day Passive Tube results for production drilling monitoring can be found in Tables 2 and 3. All 24-hour Summa Canister results for production drilling monitoring can be found in Table 4. All data analysis All results in these tables are below the Health Guidance Values (HGVs) provided in Section 11 of the HSE Air Monitoring Program. Meteorological data for the reporting period can be found in the Figure 5. Prepared by: Austin Heitmann Kerr-McGee Oil & Gas Onshore LP Report ID: 017AA-008129-RT-23 Page 12 Summary of Results Figure 1 – Te Velde 29-28HZ Southeast VOC Data The graph below is shown for the PID Analyzer installed on the Southeast side of Te Velde 29-28HZ pad (Location ID: T-9) and is plotted with 15-minute averages. Kerr-McGee Oil & Gas Onshore LP Report ID: 017AA-008129-RT-23 Page 13 Figure 2 – Te Velde 29-28HZ Southwest VOC Data The graph below is shown for the PID Analyzer installed on the Southwest side of Te Velde 29-28HZ pad (Location ID: T-13) and is plotted with 15-minute averages. Kerr-McGee Oil & Gas Onshore LP Report ID: 017AA-008129-RT-23 Page 14 Figure 3– Te Velde 29-28HZ West VOC Data The graph below is shown for the PID Analyzer installed on the West side of Te Velde 29-28HZ pad (Location ID: T-17) and is plotted with 15-minute averages. Kerr-McGee Oil & Gas Onshore LP Report ID: 017AA-008129-RT-23 Page 15 Figure 4 – Te Velde 29-28HZ East VOC Data The graph below is shown for the PID Analyzer installed on the East side of Te Velde 29-28HZ pad (Location ID: T-24) and is plotted with 15-minute averages. Kerr-McGee Oil & Gas Onshore LP Report ID: 017AA-008129-RT-23 Page 16 Table 1 – Te Velde VOC Data Analysis The table below reports the data distribution for all PID Analyzers installed at the Te Velde 29-28HZ pad. Location ID T-9 T-13 T-17 T-24 5th Percentile Value (PPM) 0.12 0.03 0.03 0.01 25th Percentile Value (PPM) 0.17 0.08 0.08 0.09 50th Percentile Value (PPM) 0.2 0.11 0.19 0.17 75th Percentile Value (PPM) 0.29 0.16 0.31 0.29 95th Percentile Value (PPM) 0.39 0.29 0.48 0.46 Maximum 15-min Average (PPM) 0.51 0.48 0.67 1.01 Kerr-McGee Oil & Gas Onshore LP Report ID: 017AA-008129-RT-23 Page 17 Figure 5 – Te Velde 29-28HZ Meteorological Data The wind rose below is shown for Te Velde 29-28HZ facility and is plotted with 15-minute averages. Te Velde 29-28HZ Wind Rose Kerr-McGee Oil & Gas Onshore LP Report ID: 017AA-008129-RT-23 Page 18 Table 2 –Passive Sampling Results The table below reports the results for all passive samplers and collocated PID analyzer data averaged over the same time period the passive samplers were collected. Locations IDs can be matched with their location on page 7. Location ID Te Velde 29-28HZ Passive Sampler Benzene (ppb) Analyzer VOC (ppm) Start Date-Time End Date-Time Acute: HGV1 9 N/A N/A N/A T9 0.137 0.25 5/14/2021-09:10 5/28/2021-09:32 T10 0.163 N/A 5/14/2021-09:15 5/28/2021-09:25 T11 0.145 N/A 5/14/2021-09:20 5/28/2021-09:22 T12 0.120 N/A 5/14/2021-09:25 5/28/2021-09:20 T13 0.162 0.11 5/14/2021-09:30 5/28/2021-09:19 T14 0.190 N/A 5/14/2021-09:35 5/28/2021-09:17 T15 0.175 N/A 5/14/2021-09:40 5/28/2021-09:15 T16 0.161 N/A 5/14/2021-09:35 5/28/2021-09:12 T17 0.167 0.15 5/14/2021-09:37 5/28/2021-09:10 T18 0.124 N/A 5/14/2021-09:40 5/28/2021-10:05 T19 0.121 N/A 5/14/2021-09:45 5/28/2021-10:00 T20 0.120 N/A 5/14/2021-09:50 5/28/2021-09:57 T21 0.122 N/A 5/14/2021-09:52 5/28/2021-09:55 T22 0.149 N/A 5/14/2021-09:54 5/28/2021-09:50 T23 0.123 N/A 5/14/2021-09:57 5/28/2021-09:47 T24 0.124 0.14 5/14/2021-10:00 5/28/2021-09:45 1 Health Guidance Values Te Velde 29-28HZ Wind Rose 5/14/21-5/28/21 Kerr-McGee Oil & Gas Onshore LP Report ID: 017AA-008129-RT-23 Page 19 Table 3 –Passive Sampling Results The table below reports the results for all passive samplers and collocated PID analyzer data averaged over the same time period the passive samplers were collected. Locations IDs can be matched with their location on page 7. Location ID Te Velde 29-28HZ Passive Sampler Benzene (ppb) Analyzer VOC (ppm) Start Date-Time End Date-Time Acute: HGV1 9 N/A N/A N/A T9 0.0950 0.22 5/28/2021-09:10 6/10/2021-11:15 T10 0.128 N/A 5/28/2021-09:15 6/10/2021-09:22 T11 0.130 N/A 5/28/2021-09:17 6/10/2021-09:26 T12 0.115 N/A 5/28/2021-09:20 6/10/2021-09:25 T13 0.112 0.13 5/28/2021-09:22 6/10/2021-11:30 T14 0.135 N/A 5/28/2021-09:25 6/10/2021-09:28 T15 0.138 N/A 5/28/2021-09:07 6/10/2021-09:18 T16 0.161 N/A 5/28/2021-09:10 6/10/2021-09:59 T17 0.120 0.21 5/28/2021-09:11 6/10/2021-11:30 T18 0.343 N/A 5/28/2021-10:30 6/10/2021-09:47 T19 0.263 N/A 5/28/2021-10:35 6/10/2021-09:42 T20 0.174 N/A 5/28/2021-10:40 6/10/2021-09:46 T21 0.173 N/A 5/28/2021-09:30 6/10/2021-09:36 T22 0.173 N/A 5/28/2021-09:35 6/10/2021-09:35 T23 0.137 N/A 5/28/2021-09:40 6/10/2021-09:31 T24 0.107 0.28 5/28/2021-09:45 6/10/2021-11:00 1 Health Guidance Values Te Velde 29-28HZ Wind Rose 5/28/21-6/10/21 Kerr-McGee Oil & Gas Onshore LP Report ID: 017AA-008129-RT-23 Page 20 Table 4 –Summa Canister Results and Rig Activity SUMMA® canisters were placed at the monitor locations during the sampling period. The tables below report the completions activity and the results for the SUMMA® canisters and collocated PID analyzer VOC data averaged over the same time period the canisters were collected. Te Velde 29-28HZ 6/16-17/2021 Production Rig Drilling – Drilling lateral section of well Location ID Te Velde 29-28HZ SUMMA® Canister Results (ppb) Analyzer VOC (ppm) Start Date- Time End Date- Time Benzene Toluene Ethylbenzene m-/p- Xylenes o- Xylene Acute: HGV1 9 2,000 5,000 2,000 N/A N/A N/A T-9 0.234 0.609 0.121 0.442 0.172 0.31 6/16/21- 1014 6/17/21- 0919 T-13 0.172 0.338 <0.106 0.143 <0.107 0.33 6/16/21- 1001 6/17/21- 0904 T-172 N/A N/A N/A N/A N/A 0.54 6/16/21- 0957 6/17/21- 0907 T-24 0.191 0.415 <0.0977 0.268 0.102 0.32 6/16/21- 1009 6/17/21- 091 1 Health Guidance Values 2 Sample T-17 was received at the lab with a full vacuum still on the summa canister indicating no sample was collected, either due to a malfunctioning canister sampler or some other field error. This resulted in a “VOID” sample and was not analyzed. Te Velde 29-28HZ Wind Rose 6/16/21-6/17/21 Appendix A: Calibration and QA/QC Data Linearity Check Bottle Value (PPM) Actual Linearity Check Monitor Response Baseline Match Adjustment (PPM) Mid Response Error Zero Span Zero Span Offset Gain Mid Mid (PPM)Offset Mid (25%)#1 #2 #3 #4 #5 #6 #7 Zero Mid Span Zero Mid Span Mid (25%) 5/13/2021 0.00 4.80 54.85 232.21 -54.850 0.02706 3.02 2.70 0.00 10.6%2.70 2.70 2.70 2.70 2.70 2.69 2.69 0.005 0.015 6/10/21 3.03 3.34 10.2%Te Velde-W SPOD1069 5/13/2021 0.00 4.80 54.85 232.21 -54.850 0.02706 3.02 2.70 0.00 10.6%2.70 2.70 2.70 2.70 2.70 2.69 2.69 0.005 0.015 7/9/21 3.02 4.04 33.8%Te Velde-W SPOD1069 7/9/2021 0.00 4.84 66.44 283.44 -66.440 0.02230 3.02 3.07 0.15 1.7%3.09 3.10 3.11 3.11 3.12 3.11 3.11 0.010 0.029 Pad-Direction Unit ID MET Direction Check, if applicable (Pass/Fail) 7-Iteration Mid Concentration Reading for DL Calculation (PPM) Std Deviation (PPM) Detection Limit as 3*SD (PPM) (<0.05 PPM)Date Bottle Value Pre-Monitoring Post-Monitoring Date Bottle Value Pre- Monitoring (mV)New Post-Monitoring (TVOC (PPM)) Linearity Check Bottle Value (PPM) Actual Linearity Check Monitor Response Baseline Match Adjustment (PPM) Mid Response Error Zero Span Zero Span Offset Gain Mid Mid (PPM)Offset Mid (25%)#1 #2 #3 #4 #5 #6 #7 Zero Mid Span Zero Mid Span Mid (25%) 5/13/2021 0.00 4.80 52.33 217.17 -52.330 0.02913 3.02000 2.51000 0.00 16.9%2.51 2.51 2.51 2.51 2.50 2.50 2.50 0.005 0.016 6/10/21 3.03 3.38 11.6%Te Velde-SE SPOD1065 Pass 5/13/2021 0.00 4.80 52.33 217.17 -52.330 0.02913 3.02000 2.51000 0.00 16.9%2.51 2.51 2.51 2.51 2.50 2.50 2.50 0.005 0.016 7/9/21 3.02 3.04 0.7%Te Velde-SE SPOD1065 Pass 5/13/2021 0.00 4.80 52.33 217.17 -52.330 0.02913 3.02000 2.51000 0.00 16.9%2.51 2.51 2.51 2.51 2.50 2.50 2.50 0.005 0.016 Pad-Direction Unit ID MET Direction Check, if applicable (Pass/Fail) 7-Iteration Mid Concentration Reading for DL Calculation (PPM)Std Deviation (PPM) Detection Limit as 3*SD (PPM) (<0.05 PPM)Date Bottle Value Pre-Monitoring Post-Monitoring Date Bottle Value Pre- Monitoring (mV)New Post-Monitoring (TVOC (PPM)) Linearity Check Bottle Value (PPM) Actual Linearity Check Monitor Response Baseline Match Adjustment (PPM) Mid Response Error Zero Span Zero Span Offset Gain Mid Mid (PPM)Offset Mid (25%)#1 #2 #3 #4 #5 #6 #7 Zero Mid Span Zero Mid Span Mid (25%) 5/13/2021 0.00 4.80 54.36 248.32 -54.360 0.02475 3.02000 2.40000 0.00 20.5%2.39 2.40 2.40 2.40 2.40 2.41 2.41 0.007 0.021 6/10/21 3.03 2.68 11.6%Te Velde-SW SPOD1114 5/13/2021 0.00 4.80 54.36 248.32 -54.360 0.02475 3.02000 2.40000 0.00 20.5%2.39 2.40 2.40 2.40 2.40 2.41 2.41 0.007 0.021 7/9/21 3.02 2.88 4.6%Te Velde-SW SPOD1114 5/13/2021 0.00 4.80 54.36 248.32 -54.360 0.02475 3.02000 2.40000 0.00 20.5%2.39 2.40 2.40 2.40 2.40 2.41 2.41 0.007 0.021 Pad-Direction Unit ID MET Direction Check, if applicable (Pass/Fail) 7-Iteration Mid Concentration Reading for DL Calculation (PPM) Std Deviation (PPM) Detection Limit as 3*SD (PPM) (<0.05 PPM)Date Bottle Value Pre-Monitoring Post-Monitoring Date Bottle Value Pre- Monitoring (mV)New Post-Monitoring (TVOC (PPM)) Linearity Check Bottle Value (PPM) Actual Linearity Check Monitor Response Baseline Match Adjustment (PPM) Mid Response Error Zero Span Zero Span Offset Gain Mid Mid (PPM)Offset Mid (25%)#1 #2 #3 #4 #5 #6 #7 Zero Mid Span Zero Mid Span Mid (25%) 5/13/21 0.00 4.80 55.44 179.17 -55.440 0.03882 3.00000 2.68000 0.00 10.7%2.66 2.66 2.66 2.68 2.68 2.68 2.67 0.010 0.030 6/10/21 3.03 3.54 16.8%Te Velde-E SPOD1060 6/9/21 0.00 4.84 57.48 260.95 -57.480 0.02379 3.02000 2.80000 0.00 7.3%2.80 2.80 2.80 2.80 2.80 2.80 2.80 0.000 0.000 7/9/21 3.02 2.88 4.6%Te Velde-E SPOD1083 6/9/21 0.00 4.84 57.48 260.95 -57.480 0.02379 3.02000 2.80000 0.00 7.3%2.80 2.80 2.80 2.80 2.80 2.80 2.80 0.000 0.000 Pad-Direction Unit ID MET Direction Check, if applicable (Pass/Fail) 7-Iteration Mid Concentration Reading for DL Calculation (PPM) Std Deviation (PPM) Detection Limit as 3*SD (PPM) (<0.05 PPM)Date Bottle Value Pre-Monitoring Post-Monitoring Date Bottle Value Pre- Monitoring (mV)New Post-Monitoring (TVOC (PPM)) Appendix B: Field Data Sheets Appendix C: Calibration Gas Certification Sheets CERTIFICATE OF ANALYSIS Grade of Product: CERTIFIED STANDARD-SPEC Customer:MONTROSE ENVIRONMENTAL Part Number:X02AI99C80A00F4 Reference Number:163-402092037-1 Cylinder Number:BLM003281 Cylinder Volume:84.6 CF Laboratory:124 - Pasadena (SG06) - TX Cylinder Pressure:2214 PSIG Analysis Date:May 07, 2021 Valve Outlet:590 Lot Number:163-402092037-1 Expiration Date:May 07, 2024 Product composition verified by direct comparison to calibration standards traceable to N.I.S.T. weights and/or N.I.S.T. Gas Mixture reference materials. ANALYTICAL RESULTS Component Req Conc Actual Concentration Analytical (Mole %)Uncertainty ISOBUTYLENE 3.000 PPM 3.020 PPM +/- 5% AIR Balance Airgas Specialty Gases Airgas USA, LLC 9810 BAY AREA BLVD Pasadena, TX 77507 Airgas.com Signature on file Approved for Release Page 1 of 163-402092037-1 CERTIFICATE OF ANALYSIS Grade of Product: CERTIFIED STANDARD-SPEC Part Number:X02AI99C80A00F6 Reference Number:160-402092035-1 Cylinder Number:ET0027440 Cylinder Volume:84.6 CF Laboratory:124 - Plumsteadville - PA Cylinder Pressure:2214 PSIG Analysis Date:Apr 29, 2021 Valve Outlet:590 Lot Number:160-402092035-1 Expiration Date:Apr 29, 2024 Product composition verified by direct comparison to calibration standards traceable to N.I.S.T. weights and/or N.I.S.T. Gas Mixture reference materials. ANALYTICAL RESULTS Component Req Conc Actual Concentration Analytical (Mole %)Uncertainty ISOBUTYLENE 5.000 PPM 4.840 PPM +/- 5% AIR Balance Airgas Specialty Gases Airgas USA, LLC 6141 Easton Road Bldg 2 Plumsteadville, PA 18949 Airgas.com Signature on file Approved for Release Page 1 of 160-402092035-1 Appendix D: API and AIRS Numbers Well API# Latitude Longitude TE VELDE 28-1HZ TE VELDE 28-3HZ TE VELDE 28-6HZ TE VELDE 28-7HZ TE VELDE 28-9HZ 40.1156330 40.1010002 40.1009922 10.1009886 40.1009841 -104.8998650 -104.9025407 -104.8994831 -104.8985069 -104.8965758 0512350689 0512350697 0512350696 0512350694 0512350693  Te Velde 29-28HZ Pad Production Facility AIRS number 123A0D8001 for the permanent water tanks. Appendix E: Operations Activity Te Velde 29-28HZ Pad Operational Activity Date Activity 6/6 – 23/2021 Production Rig Drilling 6/24 – 30/2021 DUCs Monitoring Appendix F: Investigation Level Event Descriptions No investigation level event occurred during this reporting period. 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