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HomeMy WebLinkAboutTe Velde 29-28HZ - Air Monitoring Program/Report - Kerr McGee - 2/28/2022 February 28, 2022 Kerr-McGee Oil & Gas Onshore LP 1099 18th Street Denver, CO 80202 720-929-6000 Marty Ostholthoff - LGD and Planning Manger Nancy D. Chick 151 Grant Avenue Physical Science Researcher P.O. Box 100 CDPHE Firestone, CO 80520 4300 Cherry Creek Drive S. Denver, CO 80246-1530 Mr. Taylor Robinson Environmental Health Specialist Mr. Jason Maxey OGED Director and Local Government Designee Oil & Gas Energy Department 1301 N. 17th Ave. Greeley, CO 80631 Re: Air Monitoring Program: Te Velde 29-28HZ Pad and Production Facility Weld County, Colorado In accordance with CDPHE Regulation 7 VI.C.2.b, Kerr-McGee is submitting the Air Monitoring Report for operations during January 2022 for this location. Kerr-McGee has contracted Montrose Air Quality Services, LLC (Montrose) to perform the air monitoring at this location. Attached is the Air Monitoring Report prepared by Montrose. Air Monitoring was conducted in accordance with the Kerr-McGee Air Monitoring Program approved by CDPHE in a letter dated April 20, 2021. All analytical results included in this report are below the health guidance values (HGVs) guidelines compiled by the Colorado Department of Public Health and Environment (CDPHE). The Air Monitoring Program establishes three (3) levels of investigation responses to ensure protection of public health, safety, welfare, the environment, and wildlife resources. Sections 14 and 15 of the air monitoring program detail these levels and responses. If a Level 3 event occurs, Kerr-McGee will notify the CDPHE and local government with jurisdiction over this pad within 48 hours of receiving notification. There were no readings from the continuous PID analyzers or analytical results above the Investigation Levels. If you have any questions, please contact Chad Schlichtemeier at Chad_Schlichtemeier@oxy.com. AMBIENT MONITORING REPORT TE VELDE 29-28HZ PAD PRODUCTION FACILITY PHASE KERR-MCGEE OIL & GAS ONSHORE LP Prepared For: Kerr-McGee Oil & Gas Onshore LP 1099 18th Street Denver, Colorado 80202 Prepared By: Montrose Air Quality Services, LLC 990 W. 43rd Avenue Denver, Colorado 80211 Document Number: 085AA-008199-RT-6 Reporting Period: January 1 through January 31, 2022 Production Facility Monitoring: September 4, 2021 through March 6, 2022 Report Date: February 28, 2022 Kerr-McGee Oil & Gas Onshore LP Report ID: 085AA-008199-RT-6 Page 2 Table of Contents PROJECT OVERVIEW ............................................................................................................................... 3 Summary ...................................................................................................................................................... 3 Contact Information .................................................................................................................................... 3 Well Pad Site Description............................................................................................................................ 3 Sampling Locations for Production Monitoring .......................................................................................... 3 Methodology ................................................................................................................................................ 5 Phase of Operation and Activities During Reporting Period ...................................................................... 6 Summary of Down Time or Equipment Malfunction ................................................................................... 6 Summary of Investigations and Response .................................................................................................... 6 Discussion of Results ................................................................................................................................... 7 SUMMARY OF RESULTS .......................................................................................................................... 8 Figure 1 – Te Velde 29-28HZ Southeast (T-9) VOC Data .......................................................................... 8 Figure 2 – Te Velde 29-28HZ Southwest (T-13) VOC Data ........................................................................ 9 Figure 3– Te Velde 29-28HZ West (T-17) VOC Data ............................................................................... 10 Figure 4 – Te Velde 29-28HZ East (T-24) VOC Data ............................................................................... 11 Table 1 – Te Velde VOC Data Analysis ..................................................................................................... 12 Figure 5 – Te Velde 29-28HZ Meteorological Data ................................................................................. 13 Table 2 –Passive Sampling Results ........................................................................................................... 14 Table 3–Passive Sampling Results ............................................................................................................ 15 APPENDIX A: CALIBRATION AND QA/QC DATA APPENDIX B: FIELD DATA SHEETS APPENDIX C: CALIBRATION GAS CERTIFICATION SHEETS APPENDIX D: API AND AIRS NUMBERS APPENDIX E: OPERATIONS ACTIVITY APPENDIX F: INVESTIGATION LEVEL EVENT DESCRIPTIONS Kerr-McGee Oil & Gas Onshore LP Report ID: 085AA-008199-RT-6 Page 3 Project Overview Summary Montrose Air Quality Services, LLC (Montrose) was contracted by Kerr-McGee Oil & Gas Onshore LP (Kerr-McGee) to conduct air monitoring at the Te Velde 29-28HZ Pad. This report covers the reporting period from January 1 through January 31, 2022 for production facility operations. Air Monitoring was conducted in accordance with the Kerr-McGee Air Monitoring Program approved by CDPHE in a letter dated April 20, 2021. All air samples taken during the reporting period were well below the Health Guidance Values (HGVs) compiled by the CDPHE. There were no readings from the continuous PID analyzers or analytical results above the Investigation Levels. Contact Information The contact information for each of the principal parties is summarized in the tables below: Chad Schlichtemeier James Garrett Oxy USA Inc. Montrose Air Quality Services, LLC 1099 18th Street 990 West 43rd Ave Denver, CO 80202 Denver, CO 80216 Phone: (720) 929-6867 Phone: (303) 670-0530 E-mail: Chad_Schlichtemeier@Oxy.com E-mail: JaGarrett@Montrose-Env.com Well Pad Site Description The Kerr-McGee Te Velde 29-28HZ well pad facility location. Latitude Longitude Te Velde 29-28HZ Pad 40.115633 -104.899865 Parent Well Code 1123051235068 Legal Description: NNW 28 2N 67W 6 PM The API number of the wells and any associated facility or equipment AIRS numbers can be found in Appendix D. Sampling Locations for Production Monitoring Sampling locations are labeled by ID on the map below. Kerr-McGee Oil & Gas Onshore LP Report ID: 085AA-008199-RT-6 Page 4 The GPS coordinates of the locations are listed in the following table. Location ID GPS Coordinates Distance from Facilities (ft) Monitoring Technology T9 40.11406, -104.89612 300 PID Analyzer, Carbon Sorbent Tube T13 40.114051, -104.901119 300 PID Analyzer, Carbon Sorbent Tube T17 40.115577, -104.901473 250 PID Analyzer, Carbon Sorbent Tube, Meteorological Station T24 40.115504, -104.896630 300 PID Analyzer, Carbon Sorbent Tube Kerr-McGee Oil & Gas Onshore LP Report ID: 085AA-008199-RT-6 Page 5 Methodology Continuous Monitoring The monitoring on the perimeter of the well pad is being performed using PID VOC analyzers. The PID analyzers used at this location are manufactured by Lunar Outpost (Canary-S), a Golden, Colorado company and SENSIT (SPOD), an Indiana company. In the device sampling occurs by allowing the ambient air to passively enter the devices exterior housing via small holes and pass over the surface of the sensor. Each device used in this project is solar powered and transmits data via cellular. A PID sensor contains a lamp that produces photons that carry enough energy to break molecules into ions. The PID will only respond to molecules that have an ionization energy at or below the energy of the lamp, the PID used on this project employs a 10.6 electron- volt lamp. The produced ions then generate an electrical current that is measured as the output of the detector. The PID used in this monitoring campaign is manufactured by IonScience, a United Kingdom company. The sensor mitigates the traditional PID issue of humidity bias, by installing a hydrophobic filter between the lamp and the ambient air. Water molecules are deterred from entering the ion producing chamber and absorbing radiation. The PID themselves are also heated slightly above ambient temperature to improve stability of the detector. All continuous monitoring equipment operation and maintenance procedures followed the Quality Assurance Project Plan provided in the Kerr-McGee Air Monitoring Program. Carbon Sorbent Tubes For the passive sorbent tube sampling portion of this test program, EPA Method 325A/B entitled “Volatile Organic Compounds from Fugitive and Area Sources” was followed for both sampling and analysis methodology. The study incorporated passive sampling for Benzene utilizing Carbopack X™ tubes. The tube is a stainless steel net cylinder, with 100 mesh grid opening and 5.8 mm diameter, packed with 530 ± 30 mg of activated charcoal with particle size 35-50 mesh. Volatile organic compounds are trapped by adsorption. The tube is desorbed using a thermal desorber and the extract is analyzed using GC/MS. Benzene concentrations are calculated using the mass of each compound found, the validated Carbopack X™ uptake rates, time sampled, and average field temperature. Field-ready passive samplers were provided in a background-free cooler by Enthalpy Analytical, LLC (Enthalpy) in Durham, North Carolina. Tubes are individually packaged in sealed glass vials, providing protection against contamination. The cooler includes ice packs to keep the sampled tubes cool throughout the shipping process. All Carbon Sorbent Tube field sampling followed the SOP provided in the Kerr-McGee Air Monitoring Program. Kerr-McGee Oil & Gas Onshore LP Report ID: 085AA-008199-RT-6 Page 6 SUMMA® Canister For the summa canister sampling portion of this test program, EPA Compendium Method TO-15 entitled “Determination of Volatile Organic Compounds (VOCs) in Air Collected in Specially Prepared Canisters and Analyzed by Gas Chromatography/Mass Spectrometry (GC/MS)” (“Method TO-15”) was followed for both sampling and analysis methodology. Entech Instruments Silonite™ CS1200E Passive Canister Samplers were used to collect samples over each 24-hour period. The Entech canisters used were six-liter stainless canisters lined with ultra-inert surface coatings. The canisters were cleaned and blanked for use according to laboratory standard operating procedures. The canister samples were shipped to the Enthalpy laboratory where the samples were analyzed for benzene, toluene, ethylbenzene, and xylenes. All SUMMA® canister field sampling followed the SOP provided in the Kerr-McGee Air Monitoring Program. Phase of Operation and Activities During Reporting Period In Appendix E is the operational activity during the reporting period. Summary of Down Time or Equipment Malfunction The PID Analyzers data recovery, which includes equipment malfunctions, during the reporting period are shown in the table below. Location ID T-9 T-13 T-17 T-24 Data Recovery (%) 98.0% 99.4% 99.4% 99.4% The post-monitoring bump test results for January were outside the range set forth in the Quality Assurance Project Plan (QAPP) on the PID analyzers on the East side of the Well Pad (Location ID: T-24). The procedures outlined in the QAPP, which is part of the approved Kerr-McGee Air Monitoring Program, were followed. A full three-point calibration was conducted on the unit and the analyzer was thoroughly inspected. The equipment passed QA/QC checks and the bump test demonstrated the unit was still linear. The unit seemed to have drifted more than is typical over a one-month period, which is not unusual for monitors of this type. The data collected on analyzer T-24 is considered valid, and the analytical data collected during this reporting period does not indicate any abnormal site operations. Summary of Investigations and Response The Kerr-McGee Air Monitoring Program establishes Investigation Levels for the continuous monitors and analytical results. If an Investigation Level is triggered, the monitoring program outlines an Investigation Level Response for each level. Kerr-McGee Oil & Gas Onshore LP Report ID: 085AA-008199-RT-6 Page 7 During this reporting period, there were no continuous monitor readings or analytical results that exceeded an Investigation Level. Investigation event responses, if applicable, can be found in Appendix F. Investigation Level 3: No notifications to CDPHE and the local government with jurisdiction over the location of the operations within forty-eight (48) hours of responsive action(s) taken as a result of recorded values in excess of the Investigation Level 3 were required. Discussion of Results The 15-minute block averages for the PID VOC results for all sampling can be found in Figures 1 through 4. The data distribution for the PID VOC results can be found in Table 1. All 14-day Passive Tube results can be found in Tables 2 and 3. All data analysis All results in these tables are below the Health Guidance Values (HGVs) provided in Section 11 of the HSE Air Monitoring Program. Meteorological data for the reporting period can be found in Figure 5. Prepared by: James Garrett Kerr-McGee Oil & Gas Onshore LP Report ID: 085AA-008199-RT-6 Page 8 Summary of Results Figure 1 – Te Velde 29-28HZ Southeast (T-9) VOC Data The graph below is shown for the PID Analyzer installed on the Southeast side of Te Velde 29-28HZ pad (Location ID: T-9) and is plotted with 15-minute averages. Kerr-McGee Oil & Gas Onshore LP Report ID: 085AA-008199-RT-6 Page 9 Figure 2 – Te Velde 29-28HZ Southwest (T-13) VOC Data The graph below is shown for the PID Analyzer installed on the Southwest side of Te Velde 29-28HZ pad (Location ID: T-13) and is plotted with 15-minute averages. Kerr-McGee Oil & Gas Onshore LP Report ID: 085AA-008199-RT-6 Page 10 Figure 3– Te Velde 29-28HZ West (T-17) VOC Data The graph below is shown for the PID Analyzer installed on the West side of Te Velde 29-28HZ pad (Location ID: T-17) and is plotted with 15-minute averages. Kerr-McGee Oil & Gas Onshore LP Report ID: 085AA-008199-RT-6 Page 11 Figure 4 – Te Velde 29-28HZ East (T-24) VOC Data The graph below is shown for the PID Analyzer installed on the East side of Te Velde 29-28HZ pad (Location ID: T-24) and is plotted with 15-minute averages. Kerr-McGee Oil & Gas Onshore LP Report ID: 085AA-008199-RT-6 Page 12 Table 1 – Te Velde VOC Data Analysis The table below reports the data distribution for all PID Analyzers installed at the Te Velde 29-28HZ pad. Location ID T-9 T-13 T-17 T-24 5th Percentile Value (PPM) 0.00 0.00 0.00 0.00 25th Percentile Value (PPM) 0.00 0.00 0.02 0.00 50th Percentile Value (PPM) 0.04 0.00 0.05 0.00 75th Percentile Value (PPM) 0.08 0.00 0.07 0.07 95th Percentile Value (PPM) 0.15 0.00 0.11 0.10 Maximum 15-min Average (PPM) 0.40 0.06 0.30 0.15 Kerr-McGee Oil & Gas Onshore LP Report ID: 085AA-008199-RT-6 Page 13 Figure 5 – Te Velde 29-28HZ Meteorological Data The wind rose below is shown for Te Velde 29-28HZ facility and is plotted with 15-minute averages. Te Velde 29-28HZ Wind Rose Kerr-McGee Oil & Gas Onshore LP Report ID: 085AA-008199-RT-6 Page 14 Table 2 –Passive Sampling Results The table below reports the results for all passive samplers that were collected. Location IDs can be matched with their location on page 4. Location ID Te Velde 29-28HZ Passive Sampler Benzene (ppb) Start Date- Time End Date-Time Acute: HGV1 9 N/A N/A T9 0.340 1/6/2022_09:30 1/21/2022_10:04 T13 0.340 1/6/2022_09:35 1/21/2022_10:08 T17 0.330 1/6/2022_09:41 1/21/2022_10:14 T24 0.366 1/6/2022_09:50 1/21/2022_10:19 1 Health Guidance Values Te Velde 29-28HZ Wind Rose 1/6/22-1/21/22 Kerr-McGee Oil & Gas Onshore LP Report ID: 085AA-008199-RT-6 Page 15 Table 3–Passive Sampling Results The table below reports the results for all passive samplers that were collected. Location IDs can be matched with their location on page 4. Location ID Te Velde 29-28HZ Passive Sampler Benzene (ppb) Start Date-Time End Date-Time Acute: HGV2 9 N/A N/A T9 0.228 12/23/2021_08:04 1/6/2022_09:30 T13 0.231 12/23/2021_08:09 1/6/2022_09:35 T17 0.216 12/23/2021_08:14 1/6/2022_09:41 T24 0.255 12/23/2021_08:20 1/6/2022_09:50 2 Health Guidance Values Te Velde 29-28HZ Wind Rose 12/23/21-1/6/22 Appendix A: Calibration and QA/QC Data Linearity Check Bottle Value (PPM) Actual Linearity Check Monitor Response Baseline Match Adjustment (PPM) Mid Response Error Zero Span Zero Span Offset Gain Mid Mid (PPM)Offset Mid (25%)#1 #2 #3 #4 #5 #6 #7 Zero Mid Span Zero Mid Span Mid (25%) 5/13/2021 0.00 4.80 54.85 232.21 -54.85 0.0271 3.02 2.70 0.00 10.6%2.70 2.70 2.70 2.70 2.70 2.69 2.69 0.005 0.015 6/10/21 3.03 3.34 10.2%T-17 SPOD1069 5/13/2021 0.00 4.80 54.85 232.21 -54.85 0.0271 3.02 2.70 0.00 10.6%2.70 2.70 2.70 2.70 2.70 2.69 2.69 0.005 0.015 7/9/21 3.02 4.04 33.8%T-17 SPOD1069 7/9/2021 0.00 4.84 66.44 283.44 -66.44 0.0223 3.02 3.07 0.15 1.7%3.09 3.10 3.11 3.11 3.12 3.11 3.11 0.010 0.029 8/9/2021 2.99 2.86 4.3%T-17 SPOD1069 7/9/2021 0.00 4.84 66.44 283.44 -66.44 0.0223 3.02 3.07 0.15 1.7%3.09 3.10 3.11 3.11 3.12 3.11 3.11 0.010 0.029 9/3/2021 2.98 2.68 10.1%T-17 SPOD1069 10/1/2021 0.00 4.89 77.61 209.6 -77.61 0.0370 2.96 2.77 0.60 13.9%2.75 2.75 2.76 2.77 2.78 2.79 2.79 0.017 0.05 10/1/2021 2.96 2.16 27.03%T-17 SPOD1069 10/1/2021 0.00 4.89 77.61 209.6 -77.61 0.0370 2.96 2.77 0.60 13.9%2.75 2.75 2.76 2.77 2.78 2.79 2.79 0.017 0.05 10/28/2021 2.95 2.60 11.9%T-17 SPOD1069 Pass 11/19/2021 0.00 4.80 59.94 184.16 -59.94 0.04 2.95 2.99 0.1 4.7%2.97 2.97 2.98 2.99 2.99 3 3.01 0.015 0.045 11/19/2021 2.95 1.95 33.9%T-17 SPOD1069 Pass 12/22/2021 0.00 4.80 61.90 150.49 -61.90 0.0542 2.90 2.83 0.3 7.9%2.80 2.80 2.82 2.83 2.83 2.8 2.83 0.014 0.042 12/22/2021 2.90 2.10 27.6%T-17 SPOD1069 Pass 12/22/2021 0.00 4.80 61.90 150.49 -61.90 0.0542 2.90 2.83 0.3 7.9%2.80 2.80 2.82 2.83 2.83 2.8 2.83 0.014 0.042 1/21/2022 4.78 4.33 9.3%T-17 SPOD1069 Pass Pre-Monitoring Post-Monitoring Date Bottle Value Pre- Monitoring (mV)New Post-Monitoring (TVOC (PPM)) Location ID Unit ID MET Direction Check, if applicable (Pass/Fail)Notes 7-Iteration Mid Concentration Reading for DL Calculation (PPM) Std Deviation (PPM) Detection Limit as 3*SD (PPM) (<0.05 PPM)Date Bottle Value Linearity Check Bottle Value (PPM) Actual Linearity Check Monitor Response Baseline Match Adjustment (PPM) Mid Response Error Zero Span Zero Span Offset Gain Mid Mid (PPM)Offset Mid (25%)#1 #2 #3 #4 #5 #6 #7 Zero Mid Span Zero Mid Span Mid (25%) 5/13/2021 0.00 4.80 52.33 217.17 -52.33 0.0291 3.02 2.51 0.00 16.9%2.51 2.51 2.51 2.51 2.50 2.50 2.50 0.005 0.016 6/10/21 3.03 3.38 11.6%T-9 SPOD1065 Pass 5/13/2021 0.00 4.80 52.33 217.17 -52.33 0.0291 3.02 2.51 0.00 16.9%2.51 2.51 2.51 2.51 2.50 2.50 2.50 0.005 0.016 7/9/21 3.02 3.04 0.7%T-9 SPOD1065 Pass 5/13/2021 0.00 4.80 52.33 217.17 -52.33 0.0291 3.02 2.51 0.00 16.9%2.51 2.51 2.51 2.51 2.50 2.50 2.50 0.005 0.016 8/9/2021 2.99 3.12 4.3%T-9 SPOD1065 Pass 8/20/2021 0.00 4.84 57.43 321.52 -57.43 0.0183 2.98 2.78 0.00 6.7%2.8 2.79 2.78 2.78 2.78 2.78 2.79 0.008 0.024 9/3/2021 2.98 2.46 17.4%T-9 SPOD9003 Pass 10/1/2021 0.00 4.89 55.62 137.8 -55.62 0.06 2.96 2.74 -0.03 7.4%2.73 2.74 2.74 2.74 2.75 2.75 2.75 0.008 0.023 10/1/2021 2.96 2.41 18.6%T-9 SPOD9003 Pass 10/1/2021 0.00 4.89 55.62 137.8 -55.62 0.06 2.96 2.74 -0.03 7.4%2.73 2.74 2.74 2.74 2.75 2.75 2.75 0.008 0.023 10/28/2021 2.95 2.91 1.4%T-9 SPOD9003 Pass 11/2/2021 0.00 4.89 60.26 280.70 -60.26 0.0222 2.96 3.07 0 3.7%3.1 3.1 3.1 3.1 3.1 3.1 3.1 0.000 0.000 11/19/2021 2.95 3.48 18.0%T-9 SPOD1226 Swapped unit due to SD card issue on 11/2/21 11/19/2021 0.00 4.80 66.28 328.90 -66.28 0.02 2.95 3.07 0.1 4.1%2.99 3.0 3.0 3.0 3.0 3.01 3.02 0.01 0.029 12/22/2021 2.90 3.67 26.6%T-9 SPOD1226 12/22/2021 0.00 4.80 74.52 353.34 -74.52 0.02 2.90 3.00 0.32 14.5%3.0 3.0 3.0 3.0 3.0 3.0 3.0 0.004 0.011 1/21/2022 4.78 4.17 12.7%T-9 SPOD1226 Pre-Monitoring Post-Monitoring Date Bottle Value Pre-Monitoring (mV)New Post-Monitoring (TVOC (PPM)) Location ID Unit ID MET Direction Check, if applicable (Pass/Fail)Notes 7-Iteration Mid Concentration Reading for DL Calculation (PPM)Std Deviation (PPM) Detection Limit as 3*SD (PPM) (<0.05 PPM)Date Bottle Value Pre-Monitoring Post-Monitoring Date Bottle Value Pre- Monit oring (mV)New Linearity Check Bottle Value (PPM) Actual Linearity Check Monitor Response Baseline Match Adjustment (PPM) Mid Response Error 7- Itera tion Mid Std Deviation (PPM) Detection Limit as 3*SD (PPM) (<0.05 PPM)Date Bottle Value Post- Moni torin g Location-ID Unit ID MET Direction Check, if applicable (Pass/Fail)Notes Zero Span Zero Span Offset Gain Mid Mid (PPM)Offset Mid (25%)#1 #2 #3 #4 #5 #6 #7 Zero Mid Span Zero Mid Span Mid (25%) 5/13/2021 0.00 4.80 54.36 248.32 -54.36 0.0247 3.02 2.40 0.00 20.5%2.39 2.40 2.40 2.40 2.40 2.41 2.41 0.007 0.021 6/10/21 3.03 2.68 11.6%T-13 SPOD1114 5/13/2021 0.00 4.80 54.36 248.32 -54.36 0.0247 3.02 2.40 0.00 20.5%2.39 2.40 2.40 2.40 2.40 2.41 2.41 0.007 0.021 7/9/21 3.02 2.88 4.6%T-13 SPOD1114 5/13/2021 0.00 4.80 54.36 248.32 -54.36 0.0247 3.02 2.40 0.00 20.5%2.39 2.40 2.40 2.40 2.40 2.41 2.41 0.007 0.021 8/9/2021 2.99 2.82 5.7%T-13 SPOD1114 5/13/2021 0.00 4.80 54.36 248.32 -54.36 0.0247 3.02 2.40 0.00 20.5%2.39 2.40 2.40 2.40 2.40 2.41 2.41 0.007 0.021 9/3/2021 2.98 2.54 14.8%T-13 SPOD1114 10/1/2021 0.00 4.887 63.29 207.46 -63.29 0.0339 2.96 2.79 0.00 5.7%2.79 2.79 2.79 2.79 2.79 2.79 2.79 0.000 0.000 10/1/2021 2.96 2.17 26.69%T-13 SPOD1114 10/7/2021 0.00 4.887 65.18 216.67 -65.18 0.0323 2.96 2.83 0.3 5.7%2.81 2.81 2.82 2.83 2.83 2.84 2.84 0.01 0.04 10/28/2021 2.95 3.29 11.5%T-13 SPOD1211 Swapped on 10/08/21 Met station was needed at another location 11/19/2021 0.00 4.80 64.48 326.67 -64.48 0.02 2.95 2.83 0.1 4.1%2.8 2.8 2.8 2.8 2.8 2.8 2.8 0.02 0.05 11/18/2021 2.95 4.89 65.80%T-13 SPOD1211 12/22/2021 0.00 4.80 51 392.7 -51.00 0.0140 2.90 2.93 0 1.0%2.9 2.9 2.9 2.9 2.9 2.9 2.9 0.01 0.04 12/22/2021 2.90 3.73 28.6%T-13 SPOD1211 12/22/2021 0.00 4.80 51 392.7 -51.00 0.0140 2.90 2.93 0 1.0%2.9 2.9 2.9 2.9 2.9 2.9 2.9 0.01 0.04 1/21/2022 4.78 4.20 12.0%T-13 SPOD1211 Linearity Check Bottle Value (PPM) Actual Linearity Check Monitor Response Baseline Match Adjustment (PPM) Mid Response Error Zero Span Zero Span Offset Gain Mid Mid (PPM)Offset Mid (25%)#1 #2 #3 #4 #5 #6 #7 Zero Mid Span Zero Mid Span Mid (25%) 5/13/21 0.00 4.80 55.44 179.17 -55.44 0.0388 3.00 2.68 0.00 10.7%2.66 2.66 2.66 2.68 2.68 2.68 2.67 0.010 0.030 6/10/21 3.03 3.54 16.8%T-24 SPOD1060 Replaced on 06.10.21 6/9/21 0.00 4.84 57.48 260.95 -57.48 0.0238 3.02 2.80 0.00 7.3%2.80 2.80 2.80 2.80 2.80 2.80 2.80 0.000 0.000 7/9/21 3.02 2.88 4.6%T-24 SPOD1083 6/9/21 0.00 4.84 57.48 260.95 -57.48 0.0238 3.02 2.80 0.00 7.3%2.80 2.80 2.80 2.80 2.80 2.80 2.80 0.000 0.000 8/9/2021 2.99 2.47 17.4%T-24 SPOD1083 8/9/2021 0.00 4.84 64.12 216.5 -64.12 0.0318 2.99 3.15 0.00 5.4%3.17 3.15 3.15 3.15 3.15 3.15 3.15 0.008 0.023 9/3/2021 2.98 2.68 10.1%T-24 SPOD1083 10/1/2021 0.00 4.887 72.37 191.2 -72.37 0.0411 2.96 2.82 0.02 4.7%2.80 2.81 2.82 2.82 2.82 2.83 2.82 0.010 0.029 10/1/2021 2.96 2.51 15.2%T-24 SPOD1083 10/1/2021 0.00 4.887 72.37 191.2 -72.37 0.0411 2.96 2.82 0.02 4.7%2.80 2.81 2.82 2.82 2.82 2.83 2.82 0.010 0.029 10/28/2021 2.95 2.86 3.1%T-24 SPOD1083 10/1/2021 0.00 4.887 72.37 191.2 -72.37 0.0411 2.96 2.82 0.02 4.7%2.80 2.81 2.82 2.82 2.82 2.83 2.82 0.010 0.029 11/19/2021 2.95 3.27 10.8%T-24 SPOD1083 10/1/2021 0.00 4.887 72.37 191.2 -72.37 0.0411 2.96 2.82 0.02 4.7%2.80 2.81 2.82 2.82 2.82 2.83 2.82 0.010 0.029 12/22/2021 2.90 2.67 7.9%T-24 SPOD1083 10/1/2021 0.00 4.887 72.37 191.2 -72.37 0.0411 2.96 2.82 0.02 4.7%2.80 2.81 2.82 2.82 2.82 2.83 2.82 0.010 0.029 1/21/2022 2.9 4.78 0.9 1.85 69.00%T-24 SPOD1083 1/21/2022 0.00 4.775 58 159.3 -58.03 0.0471 2.9 2.82 0 2.80%2.8 2.8 2.8 2.8 2.8 2.8 2.8 0 0 Pre-Monitoring Post-Monitoring Date Bottle Value Pre- Monitoring (mV)New Post-Monitoring (TVOC (PPM)) Location ID Unit ID MET Direction Check, if applicable (Pass/Fail)Notes 7-Iteration Mid Concentration Reading for DL Calculation (PPM) Std Deviation (PPM) Detection Limit as 3*SD (PPM) (<0.05 PPM)Date Bottle Value Appendix B: Field Data Sheets Appendix C: Calibration Gas Certification Sheets CERTIFICATE OF ANALYSIS Grade of Product: CERTIFIED STANDARD-SPEC Part Number:X02AI99C80A00F6 Reference Number:160-402276679-1 Cylinder Number:LL37457 Cylinder Volume:84.6 CF Laboratory:124 - Plumsteadville - PA Cylinder Pressure:2214 PSIG Analysis Date:Nov 16, 2021 Valve Outlet:590 Lot Number:160-402276679-1 Expiration Date:Nov 16, 2024 Product composition verified by direct comparison to calibration standards traceable to N.I.S.T. weights and/or N.I.S.T. Gas Mixture reference materials. ANALYTICAL RESULTS Component Req Conc Actual Concentration Analytical (Mole %)Uncertainty ISOBUTYLENE 5.000 PPM 4.775 PPM +/- 5% AIR Balance Airgas Specialty Gases Airgas USA LLC 6141 Easton Road Plumsteadville, PA 18949 Airgas.com Signature on file Approved for Release Page 1 of 160-402276679-1 Appendix D: API and AIRS Numbers Well Latitude Longitude API# TE VELDE 28-1HZ TE VELDE 28-3HZ TE VELDE 28-6HZ TE VELDE 28-7HZ TE VELDE 28-9HZ 40.1156330 40.1010002 40.1009922 10.1009886 40.1009841 -104.8998650 -104.9025407 -104.8994831 -104.8985069 -104.8965758 0512350689 0512350697 0512350696 0512350694 0512350693 ● Te Velde 29-28HZ Pad Production Facility AIRS number 123A0D8001 for the permanent water tanks. Appendix E: Operations Activity Te Velde 29-28HZ Pad Operational Activity Date Activity 1/1 –31/2022 Production Facility Activities Appendix F: Investigation Level Event Descriptions No investigation level event occurred during this reporting period. 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